Silver traded around $49 per ounce on Thursday, up from about $44 in the last week of September. The price increase and the possible crossing of the $50 threshold in the coming weeks or months are prompting the PV industry to intensify efforts to implement “thrifting,” or reducing silver content in cells and modules.
But how much can this process be pushed forward without affecting the quality of the PV products?
“This is not necessarily happening,” Ning Song, a researcher at UNSW, told pv magazine. “If silver reduction is well engineered with proper design and process control, it does not have to compromise the quality of solar cells and modules. The key is to adopt suitable approaches rather than simply cutting silver content.”
Andreas Lorenz, a researcher at Germany’s Fraunhofer ISE, also said the quality of solar products will not be impacted by silver reduction.
“A quality reduction of solar cells and modules would not be acceptable. I do not see any indication of a quality reduction, despite substantial silver reduction per cell,” said Lorenz.
Song noted that if silver reduction is not implemented properly, potential issues may include higher series resistance, reduced soldering quality, and long-term reliability concerns. “These are engineering challenges that can be effectively managed through proper metallization design and process optimization,” she said.
Lorenz explained that cell interconnection using busbarless cells with multi-wire interconnection could become challenging if finger height becomes too low, potentially causing local connection problems between wires and printed or fired contacts. “However, I am very confident that these challenges will be solved in mass production,” he added.
Song said researchers are focusing on replacing silver with cheaper metals like copper, aluminum, or nickel and on optimizing interconnection designs.
“For example, multi-busbar (MBB) and busbar-less layouts at the module level can help reduce silver consumption while maintaining performance,” she explained. “In addition, fine-line full-open stencil screen printing and copper electroplating are being actively explored as potential silver-reduction technologies.”
The scientists told pv magazine that they are convinced that the industry will intensify efforts to reduce or even replace silver with copper in the coming years.
“We believe rising silver prices are driving strong interest in alternative metallization approaches, including copper, nickel, aluminum, and various hybrid solutions,” said Song. “This is currently a very active area of both research and industrial development. In fact, some hybrid copper-silver methods have already been adopted in commercial heterojunction (HJT) solar cells. At the same time, any large-scale market shift in mainstream cell products will ultimately depend on ensuring that cell and module efficiency, long-term reliability, as well as processing cost and environmental impact, can be well managed.”
Lorenz said screen-printable copper or copper-containing pastes are the most promising method to significantly cut silver use.
“Considering the currently ongoing enormous price level boost of silver, the pressure on the PV industry to reduce silver is currently very high,” explained the Fraunhofer ISE researcher. “This will accelerate the development of new metallization pastes to replace silver with alternative materials like copper and nickel.”
Lorenz added that replacing silver pastes with copper-containing pastes in tunnel oxide passivated contact (TOPCon) solar modules is more difficult due to oxidation, copper in-diffusion, cross-contamination, and module-level reliability issues.
“My anticipation is that the very fast development of new screen/stencil generations to print ever finer contacts with less silver, particularly on the front side, will continue for some time,” Lorenz said. “However, there are limitations for further finger width reduction as the printed fingers are already very narrow. Very interesting are the current developments of fire-through copper paste for TOPCon cells, with the first tests showing very promising results on TOPCon cells. This might be a way to replace silver with copper in the long run.”
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